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Preheat broiler. Place chicken between two sheets of plastic wrap and pound to flatten. Sprinkle with salt and pepper to taste.
Spray broiler pan rack with nonstick cooking spray. Arrange chicken on rack. Broil 6 inches from heat 4 to 5 minutes per side or until done (internal temp 170°F). Cover and keep warm.
Meanwhile, make hollandaise sauce according to package directions. Cover and keep warm.
Fill a deep nonstick skillet with 3 inches of water; bring to a boil. Break 1 egg at a time into a small bowl. Swirl water in skillet and gently slide egg into water. Repeat for each egg. Cover and poach eggs 3 to 4 minutes or until yolks and whites are set. Drain well.
Top each muffin half with chicken breast and poached egg. Divide hollandaise sauce evenly over each egg and sprinkle with paprika.